This series was one of many variants of the Scooby-Doo comedy-mystery format. After being thawed out by the beautiful Teen Angels, Captain Caveman helps them solve supernatural mysteries. Most of the show's humor stems from Cavey's attempts to cope with life among 20th-century humans.
The Teen Angels travel in an orange and green van, decorated with a stylized image of an angel blowing a valveless trumpet. Captain Caveman lives inside an artificial rock formation on the roof of the van. A wooden ladder with bones for rungs provides access to the "cave".
- Mel Blanc as Captain Caveman
- Laurel Page as Taffy Dare
- Marilyn Schreffler as Brenda Chance
- Vernee Watson-Johnson as Dee Dee Skyes
These episodes were originally part of Scooby's All-Star Laff-a-Lympics.
- The Kooky Case of the Cryptic Keys
- The Mixed-Up Mystery of Deadman's Reef
- What a Flight for a Fight
- The Creepy Case of the Creaky Charter Boat
- Big Scare in the Big Top
- Double Dribble Riddle
- The Crazy Case of the Tell-Tale Tape
- The Creepy Claw Caper
- Cavey and the Kabuta Clue
- Cavey and the Weirdo Wolfman
- The Disappearing Elephant Mystery
- The Fur Freight Fright
- Ride 'Em Caveman
- The Strange Case of the Creature from Space
- The Mystery Mansion Mix-Up
- Playing Footsie with Bigfoot
These were the first episodes presented when the series was spun off onto its own.
- Disco Cavey
- Muscle-Bound Cavey
- Cavey's Crazy Car Caper
- Cavey's Mexicali 500
- Wild West Cavey
- Cavey's Winter Carnival Caper
- Cavey's Fashion Fiasco
- Cavey's Missing Missile Miss-tery
- The Scarifying Seaweed Secret
- The Dummy
- Cavey and the Volcanic Villain
- Prehistoric Panic
- Cavey and the Baffling Buffalo Man
- Cavey and the Murky Mississippi Mystery
- Old Cavey in New York
- The Albino Rhino
- Kentucky Cavey
- Cavey Goes to College
- The Haunting of Hog's Hollow
- The Legend of Devil's Run
- The Mystery of the Meandering Mummy
- The Old Caveman and the Sea
- Lights, Camera … Cavey!
A manufacture-on-demand DVD set of Captain Caveman and the Teen Angels: The Complete Series was released by Warner Archive on July 23, 2013.
Cable reruns outside the United States
- The series was never aired on Teletoon in Canada, but was aired on its sister network, Teletoon Retro.
- Captain Caveman and the Teen Angels at the Big Cartoon Database